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Subchapter C. STATEWIDE HEALTH STANDARDS
Sec.
250.301. Scope.
250.302. Point of compliance.
250.303. Aquifer determination; current use and currently planned use of aquifer
groundwater.
250.304. MSCs for groundwater.
250.305. MSCs for soil.
250.306. Ingestion numeric values.
250.307. Inhalation numeric values.
250.308. Soil to groundwater pathway numeric values.
250.309. MSCs for surface water.
250.310. Minimum threshold MSCs.
250.311. Evaluation of ecological receptors.
250.312. Final report.
Cross References This subchapter cited in 25 Pa. Code § 250.2 (relating to application of remediation standards); 25 Pa. Code § 250.9 (relating to interaction with other environmental statutes); 25 Pa. Code § 250.602 (relating to risk assessment procedures); 25 Pa. Code § 250.603 (relating to exposure factors for site-specific standards); 25 Pa. Code § 250.605 (relating to sources of toxicity information); 25 Pa. Code § 250.703 (relating to general attainment requirements for soil); and 25 Pa. Code § 250.704 (relating to general attainment requirements for groundwater).
§ 250.301. Scope.
(a) This subchapter sets forth generic Statewide health standards as one of three remediation standards that a person may select. The Statewide health standards are concentrations of regulated substances associated with a specific environmental medium, and are designated as the MSCs. The values used to determine the MSCs are contained in Appendix A, Tables 14 and 6 and are the concentrations of regulated substances that shall be met to demonstrate attainment of a Statewide health standard. Appendix A, Table 5 presents the toxicological and physical parameters used to calculate the MSCs in Appendix A, Tables 14.
(b) This subchapter sets forth generic Statewide health standards for regulated substances determined by the EPA to be mutagens. Tables 14 contain Statewide health standards based upon the methodology for mutagens in § § 250.306 and 250.307 (relating to ingestion numeric values; and inhalation numeric values) for the following substances classified as mutagens:
Regulated Substance CAS Number Benzo[a]anthracene 56-55-3 Benzidine 92-87-5 Benzo[a]pyrene 50-32-8 Benzo[b]fluoranthene 205-99-2 Benzo[k]fluoranthene 207-08-9 Chrysene 218-01-9 Dibenzo[a,h]anthracene 53-70-3 Dibromo-3-chloropropane, 1,2- 96-12-8 Indeno[1,2,3-cd]pyrene 193-39-5 Methylene bis(2-chloroaniline), 4,4'- 101-14-4 Nitrosodiethylamine, N- 55-18-5 Nitrosodimethylamine, N- 62-75-9 Nitroso-N-ethylurea, N- 759-73-9 Vinyl chloride 75-01-4 (c) This subchapter sets forth minimum threshold MSCs for soil and groundwater that shall be met to demonstrate attainment of the Statewide health standards for regulated substances in Appendix A, Table 6. Minimum threshold MSCs are standards developed for regulated substances for which no chemical-specific toxicological data exist.
(d) For regulated substances which do not have an MSC for the relevant medium on Appendix A, Tables 14 or 6, the background standard or site-specific standard shall be met to qualify for a release of liability under the act.
Authority The provisions of this § 250.301 amended under sections 104(a) and 303(a) of the Land Recycling and Environmental Remediation Standards Act (35 P. S. § § 6026.104(a) and 6026.303(a)).
Source The provisions of this § 250.301 amended January 7, 2011, effective January 8, 2011, 41 Pa.B. 230. Immediately preceding text appears at serial page (285763).
§ 250.302. Point of compliance.
(a) For attainment of the Statewide health standard for groundwater, the point of compliance is the property boundary that existed at the time the contamination was discovered. Statewide health standards shall be attained at and beyond the point of compliance. The Department may determine, in writing, a point of compliance beyond the property boundary to be appropriate if one of the following situations is demonstrated:
(1) Structures are located on the property boundary which prohibit internal or external access for a drill rig.
(2) The property is a small parcel of land with limited space for onsite monitoring wells.
(3) It is not physically possible to monitor groundwater quality at the property boundary.
(4) The downgradient property was owned by the same party at the time the contamination was discovered and the use of the groundwater on the downgradient property can be controlled to prevent unacceptable exposure.
(5) For measuring compliance with the groundwater MSCs that apply to secondary contaminants.
(b) For attainment of the Statewide health standard for soil, the MSC as determined in § 250.305 (relating to MSCs for soil) shall be met at the specified depth.
(c) For the emission of regulated substances to outdoor air, the point of compliance for any applicable air quality standard shall be as specified in the air quality regulations.
Cross References The provisions of this § 250.303 amended under sections 104(a) and 303(a) of the Land Recycling and Environmental Remediation Standards Act (35 P. S. § § 6026.104(a) and 6026.303(a)).
Source The provisions of this § 250.303 amended November 23, 2001, effective November 24, 2001, 31 Pa.B. 6395; amended January 7, 2011, effective January 8, 2011, 41 Pa.B. 230. Immediately preceding text appears at serial pages (285764) to (285766).
Cross References The provisions of this § 250.304 amended under sections 104(a) and 303(a) of the Land Recycling and Environmental Remediation Standards Act (35 P. S. § § 6026.104(a) and 6026.303(a)).
Source The provisions of this § 250.304 amended November 23, 2001, effective November 24, 2001, 31 Pa.B. 6395; amended January 7, 2011, effective January 8, 2011, 41 Pa.B. 230. Immediately preceding text appears at serial pages (285766) to (285768).
Cross References The provisions of this § 250.306 issued under sections 104(a) and 303(a) of the Land Recycling and Environmental Remediation Standards Act (35 P. S. § § 6026.104(a) and 6026.303(a)).
Source The provisions of this § 250.306 amended January 7, 2011, effective January 8, 2011, 41 Pa.B. 230; corrected March 19, 2011, effective March 5, 2011, 41 Pa.B. 1458. Immediately preceding text appears at serial pages (355274) to (355278).
Cross References The provisions of this § 250.307 issued under sections 104(a) and 303(a) of the Land Recycling and Environmental Remediation Standards Act (35 P. S. § § 6026.104(a) and 6026.303(a)).
Source The provisions of this § 250.307 amended January 7, 2011, effective January 8, 2011, 41 Pa.B. 230; corrected March 19, 2011, effective March 5, 2011, 41 Pa.B. 1458. Immediately preceding text appears at serial pages (355278) to (355288).
Cross References The provisions of this § 250.308 issued under sections 104(a) and 303(a) of the Land Recycling and Environmental Remediation Standards Act (35 P. S. § § 6026.104(a) and 6026.303(a)).
Source The provisions of this § 250.308 amended January 7, 2011, effective January 8, 2011, 41 Pa.B. 230. Immediately preceding text appears at serial pages (233669) to (233671).
Cross References This section cited in 25 Pa. Code § 250.304 (relating to MSCs for groundwater); 25 Pa. Code § 250.305 (relating to MSCs for soil); 25 Pa. Code § 250.310 (relating to minimum threshold MSCs); 25 Pa. Code § 250.312 (relating to final report); 25 Pa. Code § 250.604 (relating to fate and transport modeling requirements for exposure assessments); and 25 Pa. Code § 271.1 (relating to definitions); and 25 Pa. Code § 287.1 (relating to definitions).
§ 250.309. MSCs for surface water.
(a) Any regulated discharge to surface waters shall comply with the applicable provisions of Chapters 9196, 97 (reserved), 102, 103 and 105, including antidegradation requirements, and may not cause an exceedance of the applicable water quality standards for the surface water in question.
(b) For point source discharges to surface water, compliance shall be measured at the point of discharge in accordance with limits specified in the NPDES permit.
(c) For purposes of determining compliance with surface water quality standards from a diffuse surface or groundwater discharge, the person shall determine the expected instream regulated substance concentrations, that are attributable to releases at the site, using mass balance techniques for groundwater/surface water mixing at design flow conditions.
(1) If the results indicate that surface water quality standards are being achieved, no action is required.
(2) If results indicate that surface water quality standards are not being achieved, additional sampling may be performed to help evaluate whether surface water quality standards are being achieved.
(3) If the results of the sampling indicate surface water quality standards are being met, no further action is required.
(4) If the results of the modeling, and sampling if any, indicate that surface water quality standards are not being met, the person shall perform further remedial action to attain the surface water quality standards.
(d) Except if an NPDES permit is required, for purposes of complying with surface water quality standards in a spring, the point of compliance is the point of first designated or existing use, as defined in § § 93.1, 93.4 and 93.9 (relating to definitions; Statewide water uses; and designated water uses and water quality criteria). If the point of first designated or existing use occurs in a surface water into which a spring flows, compliance with surface water quality standards shall be determined in the manner specified in subsection (c).
Cross References This section cited in 25 Pa. Code § 245.310 (relating to site characterization report); 25 Pa. Code § 250.303 (relating to aquifer determination; current use and currently planned use of aquifer groundwater); and 25 Pa. Code § 250.707 (relating to statistical tests).
§ 250.310. Minimum threshold MSCs.
(a) For regulated substances listed in Appendix A, Table 6 that are found in groundwater, the minimum threshold MSC of 5 micrograms per liter in groundwater, shall be used.
(b) For regulated substances listed in Appendix A, Table 6 that are found in soil, the lowest of one of the following values shall be used as the minimum threshold MSC:
(1) An ingestion numeric value of 100 milligrams per kilogram in soil.
(2) The soil-to-groundwater pathway numeric value throughout the soil column as determined by the methodology in § 250.308 (relating to soil-to-groundwater pathway numeric values), but substituting 5 micrograms per liter in groundwater for the groundwater MSC. The soil-to-groundwater pathway numeric value shall be calculated by using a concentration in soil at the site which does not produce a leachate in excess of the MSC for groundwater or by using a value which is 100 times the MSC for groundwater, expressed in milligrams per kilogram of soil. An equivalency demonstration under § 250.308(d) may be substituted for the soil-to-groundwater numeric value.
(c) The minimum threshold MSC in subsection (a) and the ingestion numeric value in subsection (b)(1) are calculated according to the following exposure assumption and equation: 0.50 ppb dietary intake corresponds to a 1x10-6 risk (USFDA Threshold of Regulation Final Rule July 17, 1995) assuming the substance is a carcinogen. Correcting this value (or 5.0 ppb) to the 10-5 risk level, in Statewide health standard formulation, the threshold of regulation concentrations are determined by the following exposure assumptions and calculations:
Five µg/kg (substance of concern) threshold level corresponding to 1x10-5 risk
Dietary intake 2 kg/day x 5 µg/kg (substance - 10 µg/day (daily intake of substance of concern)
For soil ingestion: 10 µg/100 mg soil or 100 mg/kg = Threshold concentration for soils
For groundwater ingestion: 10 µg/2L water = 5 µg/L - Threshold concentration for water
The provisions of this § 250.311 amended November 23, 2001, effective November 24, 2001, 31 Pa.B. 6395. Immediately preceding text appears at serial pages (233673) to (233675).
Cross References The provisions of this § 250.312 issued under sections 104(a) and 303(a) of the Land Recycling and Environmental Remediation Standards Act (35 P. S. § § 6026.104(a) and 6026.303(a)).
Source The provisions of this § 250.312 amended January 7, 2011, effective January 8, 2011, 41 Pa.B. 230. Immediately preceding text appears at serial pages (233776) to (233777).
Cross References This section cited in 25 Pa. Code § 245.313 (relating to remedial action completion report); 25 Pa. Code § 250.311 (relating to evaluation of ecological receptors); and 25 Pa. Code § 253.1 (relating to definitions).
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